Vigyan Prasar Science portal has several downloadable books in the section
Vigyan Prasar Digital Library
Registration is free. I have downloaded a book by J.B.S. Haldane and a biography of Yellapraggada Subbarow.
P.S. See also http://blogs.discovermagazine.com/loom/2011/03/28/great-science-books-for-high-school-students-the-hive-mind-speaks/#comments for recommendationa from various people. My feel is to go for names like J.B.S. Haldane even if they are dated and supplement by some modern stuff. Many more free books at ArvindguptaToys.
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